Title

Counter-ion Effects Switch Ligand Binding From C-2 to C-5 in Kinetic Carbenes Formed From an Imidazolium Salt and IrH5(PPh3)2

Document Type

Article

Publication Date

2002

Abstract

Changing the counter-anion in 2-pyridylmethyl imidazolium salts (Br, BF4, PF6, SbF6) causes their kinetic reaction products with IrH5(PPh3)2 to be switched from normal C-2 to abnormal C-5 binding.

Comments

Copyright 2002 RCS Publishing

A link to full text has been provided for authorized subscribers.

Publication Title

Chemical Communications

Published Citation

Kovacevic, A.; Gründemann, S.; Miecznikowski, J.R.; Clot, E.; Eisenstein, O.; Crabtree, R.H. “Counter-ion Effects Switch Ligand Binding From C-2 to C-5 in Kinetic Carbenes Formed From an Imidazolium Salt and IrH5(PPh3)2.” Chemical Communications, 2002, 21, 2580-2581.

DOI

10.1039/b207588c