Document Type

Article

Article Version

Publisher's PDF

Publication Date

1985

Abstract

Homogeneous nucleation rate measurements have been made on ethanol, n‐propanol, and i‐propanol vapors over a range of temperatures and supersaturations. The Becker–Doring–Zeldovitch nucleation rate expression has been scaled so as to give good agreement with the measured nucleation rates. The same scaling factors are also used to compare calculated critical supersaturations with experimental data obtained from this investigation and a variety of other sources. The agreement is good in all cases. The nucleation rate measurements and the critical supersaturation data from this investigation reveal anomalous behavior for ethanol near 260 K and for n‐propanol near 275 K.

Comments

Copyright 1985 American Institute of Physics

The final publisher PDF has been archived here with permission from the copyright holder.

https://aip.scitation.org/doi/abs/10.1063/1.448271

Publication Title

The Journal of chemical physics

Published Citation

Kacker, A., & Heist, R. H. (1985). Homogeneous nucleation rate measurements. I. Ethanol, n‐propanol, and i‐propanol. The Journal of chemical physics, 82(6), 2734-2744. https://doi.org/10.1063/1.448271.

DOI

10.1063/1.448271

Peer Reviewed

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